Heat & Thermodynamics — File 4 of 7

Temperature, heat capacity, latent heat, conduction, convection, radiation, gas laws · 18 terms

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🌡️ Heat & Thermodynamics

Heat (J (Q))

A form of energy that flows from a hotter body to a cooler body due to a temperature difference.

Heat is energy on the move — it always flows from hot to cold, never the reverse spontaneously.

Temperature (K or °C (θ))

The measure of the degree of hotness or coldness of a body — related to the average kinetic energy of its particles.

Two objects in thermal equilibrium have the same temperature, even if one has more heat energy.

Kelvin = Celsius + 273. 0 K = absolute zero.

Thermometric Property

A physical property that changes measurably and reproducibly with temperature.

Length of mercury in a thermometer, electrical resistance, colour — all thermometric properties.

Examples: length of liquid column, resistance of a wire, EMF of a thermocouple, volume of gas.

Kelvin (unit) (K)

The SI unit of temperature. 0 K is absolute zero — the lowest possible temperature.

K = °C + 273. Kelvin is always used in gas law calculations.

Heat Capacity (J/K (C))

The quantity of heat energy required to raise the temperature of a body by 1 kelvin.

A large pot of water needs more energy to heat up 1°C than a small cup — larger heat capacity.

C = Q/ΔT. Different from specific heat capacity!

Specific Heat Capacity (J/kg/K (c))

The heat energy required to raise the temperature of 1 kg of a substance by 1 kelvin.

Water has a high SHC — it takes a lot of energy to heat up. This is why the sea warms up slowly in summer.

Q = mcΔT. SHC of water = 4200 J/kg/K.

Latent Heat (J (L))

The heat energy required to change a substance from one state to another without a change in temperature.

Boiling water stays at 100°C even as you add more heat — the energy goes into changing state, not raising temperature.

L = Q/m for specific latent heat.

Specific Latent Heat (J/kg (l))

The heat energy required to change the state of 1 kg of a substance without a change in temperature.

Q = ml. Two types: fusion (solid↔liquid) and vaporisation (liquid↔gas).

Specific Latent Heat of Fusion (J/kg (Lf))

The heat needed to change 1 kg of a substance from solid to liquid at its melting point, without temperature change.

Ice melting: stays at 0°C while absorbing energy to break the crystal structure apart.

Specific Latent Heat of Vaporisation (J/kg (Lv))

The heat needed to change 1 kg of a substance from liquid to gas at its boiling point, without temperature change.

Steam burns are worse than boiling water burns — steam releases extra latent heat energy when it condenses on skin.

Conduction

The transfer of heat energy through a solid by the passing of kinetic energy from molecule to molecule, without the molecules themselves moving.

A metal spoon left in hot soup gets hot at the handle — heat travels along the metal by conduction.

Metals are good conductors because free electrons can carry energy quickly.

Convection

The transfer of heat energy through a fluid (liquid or gas) by the physical movement of the fluid itself.

Hot air rises, cold air sinks — this circulation transfers heat throughout a room from a radiator.

Only occurs in fluids. Hot fluid is less dense, rises; cool fluid sinks.

Radiation

The transfer of heat energy as electromagnetic waves (infrared), requiring no medium.

The sun heats the Earth across the vacuum of space — only radiation can travel through a vacuum.

All objects above 0 K emit radiation. Dark/matt surfaces are better absorbers and emitters.

Solar Constant

The average solar energy hitting 1 m² of Earth's atmosphere every second. Value: approximately 1.35 kW m⁻².

This is the average value — varies slightly with Earth's elliptical orbit.

U-Value (W/m²/K)

The heat energy transmitted per second through 1 m² of a material when the temperature difference between its two sides is 1 K.

Double-glazed windows have a lower U-value than single-glazed — they conduct less heat.

Lower U-value = better insulator.

Boyle's Law

For a fixed mass of gas at constant temperature, pressure is inversely proportional to volume. pV = constant.

Squeezing a sealed syringe: halve the volume, double the pressure.

pV = constant or p₁V₁ = p₂V₂. Temperature must be constant.

Archimedes' Principle

When a body is fully or partially immersed in a fluid, it experiences an upthrust equal to the weight of fluid it displaces.

A steel ship floats because it displaces a weight of water equal to its own weight.

Upthrust = weight of fluid displaced = ρVg

Law of Flotation

A floating body displaces a fluid equal in weight to its own weight.

A boat settles until the weight of displaced water exactly equals the boat's weight.